Laboratory-based grain-shape models for simulating dust infrared spectra

Analysis of thermal dust emission spectra for dust mineralogy and physical grain properties depends on laboratory-measured or calculated comparison spectra. Often, the agreement between these two kinds of spectra is not satisfactory because of the strong influence of the grain morphology on the spectra. We investigate the ability of the statistical light-scattering model with a distribution of form factors (DFF model) to reproduce experimentally measured infrared extinction spectra for particles that are small compared to the wavelength. We take advantage of new experimental spectra measured for free particles dispersed in air with accompanying information on the grain morphology. For the calculations, we used DFFs that were derived for aggregates of spherical grains, as well as for compact grain shapes corresponding to Gaussian random spheres. Irregular particle shapes require a DFF similar to that of a Gaussian random sphere with sigma=0.3, whereas roundish grain shapes are best fitted with that of a fractal aggregate of a fractal dimension 2.4-1.8. In addition we used a fitting algorithm to obtain the best-fit DFFs for the various laboratory samples. In this way we can independently derive information on the shape of the grains from their infrared spectra. For anisotropic materials, different DFFs are needed for the different crystallographic axes. This is due to a theoretical problem, which is inherent to all models that are simply averaging the contributions of the crystallographic directions.Comment: 8 pages, 8 figures, accepted by Astronomy and Astrophysic

Seed particle formation for silicate dust condensation by SiO nucleation

Clustering of the abundant SiO molecules has been discussed as a possible mechanism of seed particle formation for silicate dust in stellar outflows with an oxygen rich element mixture. Previous results indicated that condensation temperatures based on this mechanism are significant lower than what is really observed. This negative result strongly rests on experimental data on vapour pressure of SiO. New determinations show the older data to be seriously in error. Here we aim to check with improved data the possibility that SiO nucleation triggers the cosmic silicate dust formation. First we present results of our measurements of vapour pressure of solid SiO. Second, we use the improved vapour pressure data to re-calibrate existing experimental data on SiO nucleation from the literature. Third, we use the re-calibrated data on SiO nucleation in a simple model for dust-driven winds to determine the condensation temperature of silicate in stellar outflows from AGB stars. We show that onset of nucleation under circumstellar conditions commences at higher temperature than was previously found. Calculated condensation temperatures are still by about 100 K lower than observed ones, but this may be due to the greenhouse effect of silicate dust temperatures. The assumption that the onset of silicate dust formation in late-type M stars is triggered by cluster formation of SiO is compatible with dust condensation temperatures derived from IR observations.Comment: 11 pages, 11 figure

Transient dust in warm debris disks - Detection of Fe-rich olivine grains

(Abridged) Debris disks trace remnant reservoirs of leftover planetesimals in planetary systems. A handful of "warm" debris disks have been discovered in the last years, where emission in excess starts in the mid-infrared. An interesting subset within these warm debris disks are those where emission features are detected in mid-IR spectra, which points towards the presence of warm micron-sized dust grains. Given the ages of the host stars, the presence of these grains is puzzling, and questions their origin and survival in time. This study focuses on determining the mineralogy of the dust around 7 debris disks with evidence for warm dust, based on Spitzer/IRS spectroscopic data, in order to provide new insights into the origin of the dust grains. We present a new radiative transfer code dedicated to SED modeling of optically thin disks. We make use of this code on the SEDs of seven warm debris disks, in combination with recent laboratory experiments on dust optical properties. We find that most, if not all, debris disks in our sample are experiencing a transient phase, suggesting a production of small dust grains on relatively short timescales. From a mineralogical point of view, we find that enstatite grains have small abundances compared to crystalline olivine grains. The main result of our study is that we find evidences for Fe-rich crystalline olivine grains (Fe / [Mg + Fe] ~ 0.2) for several debris disks. This finding contrasts with studies of gas-rich protoplanetary disks. The presence of Fe-rich olivine grains, and the overall differences between the mineralogy of dust in Class II disks compared to debris disks suggest that the transient crystalline dust is of a new generation. We discuss possible crystallization routes to explain our results, and comment on the mechanisms that may be responsible for the production of small dust grains

Low Temperature Opacities

Previous computations of low temperature Rosseland and Planck mean opacities from Alexander & Ferguson (1994) are updated and expanded. The new computations include a more complete equation of state with more grain species and updated optical constants. Grains are now explicitly included in thermal equilibrium in the equation of state calculation, which allows for a much wider range of grain compositions to be accurately included than was previously the case. The inclusion of high temperature condensates such as Al$_2$O$_3$ and CaTiO$_3$ significantly affects the total opacity over a narrow range of temperatures before the appearance of the first silicate grains. The new opacity tables are tabulated for temperatures ranging from 30000 K to 500 K with gas densities from 10$^{-4}$ g cm$^{-3}$ to 10$^{-19}$ g cm$^{-3}$. Comparisons with previous Rosseland mean opacity calculations are discussed. At high temperatures, the agreement with OPAL and Opacity Project is quite good. Comparisons at lower temperatures are more divergent as a result of differences in molecular and grain physics included in different calculations. The computation of Planck mean opacities performed with the opacity sampling method are shown to require a very large number of opacity sampling wavelength points; previously published results obtained with fewer wavelength points are shown to be significantly in error. Methods for requesting or obtaining the new tables are provided.Comment: 39 pages with 12 figures. To be published in ApJ, April 200

Morphological effects on IR band profiles: Experimental spectroscopic analysis with application to observed spectra of oxygen-rich AGB stars

To trace the source of the unique 13, 19.5, and 28 $\mu$m emission features in the spectra of oxygen-rich circumstellar shells around AGB stars, we have compared dust extinction spectra obtained by aerosol measurements. We have measured the extinction spectra for 19 oxide powder samples of eight different types, such as Ti-compounds (TiO, TiO$_2$, Ti$_2$O$_3$, Ti$_3$O$_5$, Al$_2$TiO$_5$, CaTiO$_3$), $\alpha$-, $\gamma$-, $\chi$-$\delta$-$\kappa$-Al$_2$O$_3$, and MgAl$_2$O$_4$ in the infrared region (10 - 50 $\mu$m) paying special attention to the morphological (size, shape, and agglomeration) effects and the differences in crystal structure. Anatase (TiO$_2$) particles with rounded edges are the possible 13, 19.5 and 28 $\mu$m band carriers as the main contributor in the spectra of AGB stars, and spherically shaped nano-sized spinel and Al$_2$TiO$_5$ dust grains are possibly associated with the anatase, enhancing the prominence of the 13 $\mu$m feature and providing additional features at 28 $\mu$m. The extinction data sets obtained by the aerosol and CsI pellet measurements have been made available for public use at http://elbe.astro.uni-jena.deComment: 17 pages, 8 figures, Accepted 24 March 2009 for publication in A&

Dust Processing and Grain Growth in Protoplanetary Disks in the Taurus-Auriga Star-Forming Region

Mid-infrared spectra of 65 T Tauri stars (TTS) taken with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope are modeled using dust at two temperatures to probe the radial variation in dust composition in the uppermost layers of protoplanetary disks. Most spectra indicating crystalline silicates require Mg-rich minerals and silica, but a few suggest otherwise. Spectra indicating abundant enstatite at higher temperatures also require crystalline silicates at temperatures lower than those required for spectra showing high abundance of other crystalline silicates. A few spectra show 10 micron complexes of very small equivalent width. They are fit well using abundant crystalline silicates but very few large grains, inconsistent with the expectation that low peak-to-continuum ratio of the 10 micron complex always indicates grain growth. Most spectra in our sample are fit well without using the opacities of large crystalline silicate grains. If large grains grow by agglomeration of submicron grains of all dust types, the amorphous silicate components of these aggregates must typically be more abundant than the crystalline silicate components. Crystalline silicate abundances correlate positively with other such abundances, suggesting that crystalline silicates are processed directly from amorphous silicates and that neither forsterite, enstatite, nor silica are intermediate steps when producing either of the other two. Disks with more dust settling typically have greater crystalline abundances. Large-grain abundance is somewhat correlated with greater settling of disks. The lack of strong correlation is interpreted to mean that settling of large grains is sensitive to individual disk properties. Lower-mass stars have higher abundances of large grains in their inner regions.Comment: 84 pages, 27 figures, submitted to the Astrophysical Journal on 7 November, 200

Carbon enrichment of the evolved stars in the Sagittarius dwarf spheroidal

We present spectra of 1142 colour-selected stars in the direction of the Sagittarius Dwarf Spheroidal (Sgr dSph) galaxy, of which 1058 were taken with VLT/FLAMES multi-object spectrograph and 84 were taken with the SAAO Radcliffe 1.9-m telescope grating spectrograph. Spectroscopic membership is confirmed (at >99% confidence) for 592 stars on the basis of their radial velocity, and spectral types are given. Very slow rotation is marginally detected around the galaxy's major axis. We identify five S stars and 23 carbon stars, of which all but four carbon stars are newly-determined and all but one (PQ Sgr) are likely Sgr dSph members. We examine the onset of carbon-richness in this metal-poor galaxy in the context of stellar models. We compare the stellar death rate (one star per 1000-1700 years) to known planetary nebula dynamical ages and find that the bulk population produce the observed (carbon-rich) planetary nebulae. We compute average lifetimes of S and carbon stars as 60-250 and 130-500 kyr, compared to a total thermal-pulsing asymptotic giant branch lifetime of 530-1330 kyr. We conclude by discussing the return of carbon-rich material to the ISM.Comment: 14 pages, 10 figures, accepted MNRA

The Limiting Effects of Dust in Brown Dwarf Model Atmospheres

We present opacity sampling model atmospheres, synthetic spectra and colors for brown dwarfs and very low mass stars in two limiting case of dust grain formation: 1) inefficient gravitational settling i.e. the dust is distributed according to the chemical equilibrium predictions, 2) efficient gravitational settling i.e. the dust forms and depletes refractory elements from the gas, but their opacity does not affect the thermal structure. The models include the formation of over 600 gas phase species, and 1000 liquids and crystals, and the opacities of 30 different types of grains including corundum (Al$_2$O$_3$), the magnesium aluminum spinel MgAl$_2$O$_4$, iron, enstatite (MgSiO$_3$), forsterite (Mg$_2$SiO$_4$), amorphous carbon, SiC, and a number of calcium silicates. The models extend from the beginning of the grain formation regime well into the condensation regime of water ice (\teff= 3000 - 100 K) and encompasses the range of $\log g= 2.5 - 6.0$ at solar metallicity. We find that silicate dust grains can form abundantly in the outer atmospheric layers of red and brown dwarfs with spectral type later than M8. The greenhouse effects of dust opacities provide a natural explanation for the peculiarly red spectroscopic distribution of the latest M dwarfs and young brown dwarfs. The grainless (Cond) models on the other hand, correspond closely to methane brown dwarfs such as Gliese 229B. We also recover that the $\lambda$5891,5897\AA Na I D and $\lambda$7687,7701\AA K I resonance doublets plays a critical role in T dwarfs where their red wing define the pseudo-continuum from the $I$ to the $Z$ bandpass.Comment: 49 pages, ApJ, in press. 22 figures (included). Corrected nasty typos. Also available at http:/phoenix.physast.uga.ed